Simultaneous Equilibria in the Benzoic Acid

Simultaneous Equilibria in the benzoic AcidJekathjenani RatnakumaranSimultaneous Equilibria in the benzoic Acid Toulene -Water SystemIntroductionBenzoic hot is an evocative carboxylic bitter with molecular melodyula, C7H6O2. It appe ard as colorless crystalline solid and has a fade, pleasant odor. Benzoic acid is easily available in nature and are used as a precursor to plasticizers, and sodium benzoate. Also, it inhibits the growth of microorganisms such as yeast, mold and bacteria. It also, used as an ointment to treat the fungal diseases such as ringworm and athletes foot. This benzoic acid fucking be prepared from the bromobenzene, benzyl inebriant and benzyl chloride.The purpose of this try out is to delimitate the dispersion coefficient () and dimerization constant of the benzoic acid in counterweight of methylbenzene and piss supply. The distribution coefficient can be determined by apply the distributive law which is presumptuousness by the Nernst in 1891. T his law states that distribution of the solute either solid or liquid between devil non miscible solvents1. When the solute distributes in the two non miscible solvent at constant temperature, the solute remains in twain solvent at the same molecular conditions and past, the concentration of solute in those two non miscible solvents will be equal to the distribution constant, K. In this experiment, the two non miscible solvents are water and methylbenzene. There are triad equilibrium states occur in the system used in this experiment such as distribution equilibrium, aqueous phase equilibrium and methylbenzene phase equilibrium. These three equilibria contain benzoic acid (HBz), water (W) and Toluene (T). The distribution occurs as monomer in water and hence, there is monmer-dimer equilibrium occurs in the water and toluene phase2. From the distribution equilibrium, the distribution coefficient, can be cipher by,HBz (w)HBz (T)From the aqueous equilibrium phase, the aqueous dis sociation constant, Ka is calculated as follows,HBz (w)H+ + Bz From the toluene equilibrium phase, the aqueous dimerization constant, K2 is calculated as follows,2HBz (T)(HBz)2The total concentration of benzoic acid in Toluene (CT) and total concentration of benzoic acid in water (Cw) can determine using the formula 1 and 3, they are as follows,Cw= HBzw + H+CT= HBzT + 2(HBz)2By plotting the graph using in a higher(prenominal) place formula, the total concentrations present in both water and toluene can be determined.MethodsThis experiment was conducted by following the procedure given in the laboratory manual by the department of chemistry, Trent University.Related questions AnswersThe organise of a dimer of benzoic acid is shown below, O H- O C C O- H OAs benzoic acid has phenyl separate and it is non wintry but water is a polar solvent. Therefore, the carboxyl group in benzoic acid will be harder to form hydrogen bonding with water and simplification the interactions b etween the benzoic acid molecules. Hence it does not form a dimer with water. In the case of hexane, the hexane is non polar solvent and therefore, the benzoic acid forms dimer with hexane. In the case of methanol, as it has hydrogen bonding, it is considered as polar solvent. When it reacts with benzoic acid, it does not form a dimer of benzoic acid. Furthermore, in the case of propanone, benzoic acid does not form dimer because propanone is a polar solvent.As the titrant solution is base solution, the indicator required to give pole point is phenolphthalein. The indicator used in the titration is based on the pH values of the solutions used. In this case, as solution contains benzoic acid and its titrated against NaOH, therefore, the to bring the end point, the phenolphthalein which has pH approximately 9 is used. If the titrant is base solution, then the methyl orange, which has pH 3.5 is used to identify the end point.ResultsTable 1 represents the volume of the benzoic acid, to luene and water added in the five solutions in different fractions of the volumes.SolutionsVolume of benzoic acid in toluene Solution (ml)Volume of water added (ml)Volume of toluene required to bring total volume to atomic number 6 ml (ml)150500240501032550254155035555045Mass of the benzoic acid used = 5.000 gVolume of the NaOH used= 10 mlCalculated concentration of the NaOH = 0.018 MTable 2 represents the titrated volume of the solutions against NaOH and HCl and calculated concentrations of benzoic acid in the Toluene and Water.Solution NumberVNaOH (w)(ml)VNaOH(T) (mL)VHCl (T) (mL)CW x 10-3 (M)CT x 10-2(M)Cw (1-)CT/Cw (1-)15.835.70.34.352.700.11410.003857.013025.428.90.44.052.200.11810.003576.162534.916.40.83.671.300.12360.003225.345043.010.71.62.250.920.15450.001904.842152.25.75.01.650.800.17730.001365.8823Figure 1 represents the plot of Cw (1-) versus CT/Cw (1-).Data Analysis computationsVolume of HBz in water, V1= 0.02 LVolume of NaOH, V2= 0.0058 LConcentration of NaOH, C2= 0. 015 MConcentration of HBz, Cw= (0.0058 x 0.015) / 0.02 M= 4.35 x 10-3 MVolume of HBz in water, V1= 0.02 LVolume of NaOH + HCl, V2= 0.036 LConcentration of NaOH, C2= 0.015 MConcentration of HBz, CT= (0.036 x 0.015) / 0.02 M= 2.70 x 10-2 MBy using the below formula, the value of was calculated,The value of Ka for benzoic acid is 6.46 x 10-50.00435 2 + 6.46 x 10-5 6.46 x 10-5Using the quadratic formula, the value of is, = 0.1141Calculation of Cw (1-) for solution 1,Cw (1-)= 0.00435 (1- 0.1141)= 0.00385Calculation of CT/Cw (1-) for solution 1,CT/Cw (1-)= (0.0270) / (0.00385)= 7.013From the figure 1, the value of K2 and are as follows,Y = -0.1344 x + 5.8939 (intercept) = 0.134422K2= 5.8939K2= (5.8939 ) / (0.03613)= 163.13 MDiscussionThe experiment was conducted with careful consideration to get the result as close as to the real value. However, repayable to the some experimental demerit involved in this experiment, the calculated values are not close to the publications value. Th e calculated K2 value is 163.13 L/mol and the alpha value is 0.1344. The literature values are 260 L/mol and 1.49 respectively. Figure 1 represents the plot of Cw (1-) versus CT/Cw (1-). Based on the graph shown on figure 1, the peak is falling and then raising. When the cadence of benzoic acid decreases, the amount of concentration of toluene increases. On the contrary, the value of concentration of benzoic acid (HBz) in water is higher than the concentration of HBz in toluene. In comparison with the literature value, the calculated value has deviated from it. However, the calculated percentage error is 37 %. This is considered as large difference when compared to literature values. These differences between the calculated and literature value occurred due to the experimental error. Equipments used in this experiment were used by the previous batch. As the experiment was conducted using the pre used equipments, there might be an error in the contamination. The solution that has ma de in this experiment has to be mixed well. This will provide a more complete result. Failure to do this criterion might have resulted in the failure of result. Also, the burette reading and end point notification are considered one of the errors which lead to inaccurate result. Due to these occurrences, the experiment does not turn successful and have heavily affected the final results. Moreover, the adjustment made in the water bath and less time of tutelage the solution in the water bath also might be lead to the error in the final result. Because temperature is ne of the factor affects the dissociation of particles. Furthermore, due to the weather condition (winter), temperature and pressure changes and might not favored to conduct the experiment.ConclusionIn conclusion, the simultaneous equilibria of benzoic acid presence in the water and toluene solvent was studied by conducting this experiment. In order to get accuracy of result, the precision can be improved by more att ention on the experimental procedure and handling the equipments. Also, accurate result can be made by observing the measurements such as notifying the burette reading and end point in a proper manner.ReferencesChemistry Made Simple about Nernst dispersion Lawn Metallurgy, (2009)Ellison H.R. Simultaneous equilibria in the benzoic acid-benzene-water system, A distribution experiment 48 (2) 124 (1971). DOI 10.1021/ed048p124P.Atkins and J. de Paula, Atkins Physical Chemistry, eighth ed., W. H.Freeman and Co., New York (2006).Department of Chemistry, Laboratory Manual, Experiment G1- Heat Capacity Ratio for Gases, Trent University, Peterborough, Ontario(2014)